Oct 23, 2017 in this article i will start the first article about boilers and my idea was begin with the boiler cleaning procedures and understand a little bit more why we need cleaning the internal boiler. Ss passivating chemicals are domestically available, and these are used by circulating within the ss pipelines and boiler. The consensus is that feedwater oxygen, iron, and copper content should be very low e. Passivation is a nonelectrolytic finishing process that makes stainless steel more rustresistant. The free iron on the metal surface can initiate corrosion andor rouging. Passivation of stainless steel vessels for boilers is a recommended practice. Schematic line diagram of ash water supply to unit1 to unit7. The passivation step at the end of the chemical cleaning is generally neither long. The boiler drum pressure is raised to 40ksc and the line to be blown is warmed up. Summary of boiler and process heater test procedures, methods. New developments in passivation technology by john j. Before water enters the boiler, oxygen must be removed or corrosion can occur throughout the boiler system. The operational and safety aspects of chemical cleaning of. Learn more about industrial boiler water treatment, causes and types of boiler corrosion, boiler corrosion inhibitors.
Removal of contaminants from stainless steel surfaces, especially free iron, using chemicals. Passivation services onsite astm, asme rapid response. Mar 25, 2018 bharat heavy electricals limitedpower sector western region recommended procedure for alkali boil out of 2 x 165 tph afbc boilers at jsl, raigarh a introduction. All boilers subject to the provisions of this act shall either 1 be continuously monitored by. Why passivate stainless steel and what happens if you dont.
The feedwater system refers to deaerator, feedwater pumps, and the piping to the boiler. Boiler water treatment introduction a boiler is a closed vessel in which water under pressure is transformed into steam by the application of heat. The manufacturing process of the boilers is clearly a dirty process, and there is a large risk that the boilers will be contaminated with millscale,oils, or slag from the manufacture of the boiler. Boiler passivation wholesale, passivation suppliers alibaba. Boilout procedure watertube steam boilers preface the internal surfaces of a newly installed boiler may be contaminated with oil, grease or other protective coatings used in the manufacturing process. The passive condition on the surface of the stainless steel is obtained.
Passivation the formation of a thin, nonporous layer of magnetic iron oxide on. After passivation, various tests can be performed to verify whether passivation has been properly performed. Passivation is the removal of iron or iron oxide from the surface in the passive film or top 3 to 4 molecular layer. Chemical passivation procedures using alkalines, wetting agents, chelants, and organic or inorganic acids. Summary of boiler and process heater test procedures. A boiler s efficiency is directly related to the quality of its feedwater. Summary of boiler and process heater test procedures, methods, and reporting requirements this document provides an overview of approved methods, target pollutant units of measure, and reporting requirements for the boiler and process heater test plan. After copper and iron removal the boiler is neutralized and rinsed to. Why passivate stainless steel and what happens if you dont by.
Heating system water is hot water circulated in a closed system. The primary objective of precleaning a boiler is to remove these impurities and should always be performed on each new boiler put in service, as well as on existing. Before a boiler is put into service, it is customary to follow a precommissional chemical cleaning procedure. Nowadays condensate process contamination and or metal corrosion products from condensate. The passivation process typically uses nitric or citric acid to remove free iron from the surface. This passive layer gets damaged through heat or chemical damage due to high humidity levels. In order to carry out a thorough passivation, the boiler should be chemically clean. Banes, astro pak corporation to insure having the maximum corrosion resistance that austenitic stainless steel has to offer, the stainless steel surface must be in a passive state. Lattner boiler company new boiler boilout recommendations. Guides and recommended procedures for water treatment. Added costs grow rapidly with no or poorly applied chemical cleanings.
The other method that is occasionally used is to dissolve the deposits in a. Waterside corrosion is a major problem in steam generation systems causing. Oxygen free, alkaline boiler water converts iron to magnetite, fe 3 o 4. Steam boiler boilouts passivation boiler and pressure. Chapter 39 boiler water treatment of the many uses for energy in the united states todayin industry, in transportation, in homes and commercial buildingsthe largest portion of total use is directed toward producing steam through the combustion of fossil fuels. This will extend the life of the vessel by protecting it from corrosion. Scribd is the worlds largest social reading and publishing site. Passivation is designed to remove the small amount of free iron from the visually clean surface. The process comprises preparing a passivation solution, and adding the passivation solution after the cleaning of the boiler is passed, and circulating at 1535 deg c for 812 hours, wherein the passivation solution comprises methanol, sodium hydrogen sulfate, hydrazine. Jim robinson senior boiler consultant, trevose, pa ed baumgartner senior project sales, spokane, wa. Water tube boiler commissioning procedure and checklists. A boilers efficiency is directly related to the quality of its feedwater.
Passivation for free machining stainless steels including aisi types 420f, 430f, 440f, 203, 182fm and carpenter. The invention relates to a passivation process after chemical cleaning of a hightemperature highpressure station boiler. Standard practice for cleaning, descaling, and passivation. The stability of the passivating iron oxide layer is critically dependent on ph and temperature. The arkansas boiler safety law, act 494 of 1961, section 7, provides the following. Used to control transient heat migration can be used as a feed water tank and feed the boiler in lieu of the da can be an integral part of the da two.
The boiler is lighted up and pressured is raised to 40 kg per cm2 the sample is to be tested for hydrazine concentration and should not be less than 25 ppm after 24 hours fire should be killed and boxed up open super heater vent at 90c and boiler is drained, the second stage passivation marks completion of chemical cleaning 8 passivation. With proper operation and maintenance you can expect years of trouble free service from your new lattner boiler. Alkali boil out procedure bhel free download pdf ebook. Cn102586772b passivation process after chemical cleaning of.
In the boiler furnace, the chemical energy in the fuel is converted into heat, and it is the function of the boiler to transfer this heat to the contained water in the most efficient manner. Standard practice for cleaning, descaling, and passivation of. Such coatings must be removed since they reduce the heat transfer rate and could result in tube rupture from overheating. This article discusses when and how to chemically clean a boiler. Pickling and passivating stainless steel light scaling left on weld caps and heat tint on the surrounding parent tube surfaces can usually be removed by acid pickling.
A twostep procedure can provide the best possible corrosion resistance. Before water enters the boiler, oxygen must be removed or corrosion can occur throughout the boiler system, forming pits that eat away at the metal. Hot alkaline treatment selection, solventacid cleaning selection hydrochloric acid, citric acid, ethylenediaminetetraaceticacid edta, sulfuric acid, sulfamic acid, and highpressure water jetting hpwj. Standard practice for cleaning, descaling, and passivation of stainless steel parts, equipment, and systems1 this standard is issued under the. Boiler chemical cleaning and treatment selection consist of following stages ex. Passivation is the process of treating the metal with acids in order to remove the free iron from the surface of the metal and coat it with this corrosionpreventing.
Oct 01, 2003 passivation also can remove sulfides exposed on the surface of free machining stainless alloys. Condensate is condensed steam which has been cooled in the plant heating or process system and returned to the boiler system. Pdf preoperational cleaning requirements for hrsg units. Boiler passivation boiler energy conversion scribd. Boiler inspections are dirty, usually hot and wet, confining and always a. Follow the boiler manufacture s cool down procedure and be sure to rinse. Jan 26, 2017 pickling, passivation and their advantages. Use the procedure in step 3 of this section to obtain a. Books covers many topics like power plants, water treatment, steam turbines, health and safety, mechanical and electrical technology. Deposit unwanted solid matter, which separates out of fluids in a process stream. Boiler chemical cleaning is something that most of us would rather not think about but that we all agree is necessary. Lattner boiler company new boiler boilout recommendations lattner boiler company. Feb 16, 20 edta cleaning processalkali flushing procedure alkali flushing alkali solution made by adding tsp0. Derouging uses stronger acids to remove large visible accumulations of iron oxides to a visually clean condition.
One can reference industry standards astm a380 and astm a967 for guidance on the procedure to be followed. This results an inert, protective oxide layer that is less likely to chemically react with air and cause corrosion. Such coatings must be removed since they reduce the heat transfer. Use of ammoniated citric acid for the chemical cleaning of high pressure boilers. Boilout procedure steam boilers preface the internal surfaces of a newly installed boiler may be contaminated with oil, grease or other protective coatings used in the manufacturing process. Surfaces must be free of grease and dirt before using these acid treatments. The primary objective of precleaning a boiler is to remove these impurities and should. Reducing corrosion and potential boiler failure with.
New lattner boiler boilout recommendations with proper operation and maintenance you can expect years of trouble free service from your new lattner boiler. This will cause pitting unless the valve and the t are replaced with stainless steel. The internal surfaces of a boiler in contact with water and steam must be kept clean and free of deposits to assure efficient heat transfer in the generation of steam. Say when you talk about a boiler, carbon steel tubes in generating section will have a reduced oxide in a state of magnetite.
In order to minimize boiler system corrosion, an understanding of the operational. Cn102586772b passivation process after chemical cleaning. Draining of the passivation solution from the boiler filling the boiler up with layup chemicals if the unit is not being returned to service. Preheating of the boiler isolating the unit to be cleaned from other units in the plant maintaining circulation during the cleaning process back flushing the economizer andor superheater draining the chemical solvent from the boiler filling the boiler with a passivation solution. This method prevents high concentrations of free sodium hydroxide from. Describe process of pre operation chemical cleaning of boiler and. Passivation is the process of treating the metal with acids in order to remove the free iron from the surface of the metal and coat it with this corrosionpreventing oxide layer. Edta cleaning passivation free download as powerpoint presentation. Migratory magnetite deposits on the protective layer and is normally gray to black in color. Summary of boiler and process heater test procedures, methods, and reporting requirements this document provides an overview of approved methods, target pollutant units of measure, and.
The alkali boil out of a boiler is carried out in order to clean the internal surfaces of the watertouched parts from oil, grease, rust, silica and other adhered impurities b scope. Hh 056 h2o2 passivation procedure page 1 of 8 technical. In the case of edta, passivation occurs after cooling the boiler to 160f and. Passivation is designed to remove the small amount of free. The initial cleaning of a new boiler or pipework is critical to its operational success. Passivation of stainless origins of islamic pdf steel. The procedure for correct operation and care of your unit is not complicated, nor is it time consuming.
Back to startup back to onsite services chemical clean and passivation. In this article i will start the first article about boilers and my idea was begin with the boiler cleaning procedures and understand a little bit more why we need cleaning the internal boiler. Both pickling and passivation are chemical treatments applied to the surface of stainless steel to remove contaminants and assist the formation of a continuous chromiumoxide, passive film. Water tube boiler commissioning procedure and checklists september 7, 2017 boiler articles, boiler commissioning, power plant articles, water tube boilers leave a comment 15,448 views the operation of checking the equipment and tuning them before putting into commercial operation is commonly termed as commissioning. A newly constructed boiler will be contaminated by particulate debris, oils and greases, and rust. Patchy, uneven pickled surfaces can result if surfaces are not clean before the acid treatment. Edta cleaning processalkali flushing procedure alkali flushing alkali solution made by adding tsp0. If these products are not removed, corrosion will occur.
Stainless steels resist corrosion best if they are clean and smooth. Welcome to boiler and mechanical power digital library and training videos library. Chemical clean, passivation new boiler cleaning pipe work. With this one batch of edta chemical solution is ready for filling into the boiler. Several methods can be used to determine the need to chemically clean a boiler. Boiler commissioning free download as powerpoint presentation. With a good passivation procedure, elemental chrome to iron ratios in the range of 0.
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